Authors
Alexander H Ip, Susanna M Thon, Sjoerd Hoogland, Oleksandr Voznyy, David Zhitomirsky, Ratan Debnath, Larissa Levina, Lisa R Rollny, Graham H Carey, Armin Fischer, Kyle W Kemp, Illan J Kramer, Zhijun Ning, André J Labelle, Kang Wei Chou, Aram Amassian, Edward H Sargent
Publication date
2012/9
Journal
Nature nanotechnology
Volume
7
Issue
9
Pages
577-582
Publisher
Nature Publishing Group UK
Description
Colloidal quantum dot (CQD) films allow large-area solution processing and bandgap tuning through the quantum size effect,,,,,. However, the high ratio of surface area to volume makes CQD films prone to high trap state densities if surfaces are imperfectly passivated, promoting recombination of charge carriers that is detrimental to device performance. Recent advances have replaced the long insulating ligands that enable colloidal stability following synthesis with shorter organic linkers or halide anions,,,,, leading to improved passivation and higher packing densities. Although this substitution has been performed using solid-state ligand exchange, a solution-based approach is preferable because it enables increased control over the balance of charges on the surface of the quantum dot, which is essential for eliminating midgap trap states,. Furthermore, the solution-based approach leverages recent progress in …
Total citations
20122013201420152016201720182019202020212022202320241314820618415815112710910795646523
Scholar articles
AH Ip, SM Thon, S Hoogland, O Voznyy, D Zhitomirsky… - Nature nanotechnology, 2012