Authors
Yi Wai Chiang, Karel Ghyselbrecht, Rafael M Santos, Boudewijn Meesschaert, Johan A Martens
Publication date
2012/8/1
Journal
Catalysis Today
Volume
190
Issue
1
Pages
23-30
Publisher
Elsevier
Description
Municipal solid waste incinerator (MSWI) bottom ash (BA) was converted to zeolitic-type adsorbent materials by hydrothermal conversion under strongly alkaline conditions. The conversion product was determined to be a mixture of sodium aluminum silicate hydrate (SASH) (Na2O·Al2O3·1.68SiO2·1.73H2O) and tobermorite (Ca5Si6O16(OH)2·4H2O). The BET specific surface area was 22.1m2/g, which represented a significant gain compared to the BA (4.6m2/g) due to the formation of micropores and mesopores. The converted BA demonstrated promising performance for application as a sorbent towards several heavy metals (oxyanions of As(V), and Cd2+, Co2+, Ni2+, Pb2+, and Zn2+). Its performance was found to be generally superior to that of a mainly clinoptilolite natural zeolite, achieving greater sorption extents and better stabilizing capability of contaminated sediments. At a lower dosage rate (50mg …
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