View article

Colors of plinian pumices were measured by spectrocolorimetry, and their quantitative color parameters in the L*a*b* color space were determined. A series of heating experiments of obsidian was conducted to simulate the color-change processes of rhyolitic glasses. In these experiments, following three stages of color-change processes were observed. Stage I showed a rapid b* (yellowishness) increase associated with fast dehydration controlled by water diffusivity (D _water). In stage II, a* (reddishness) increase was accompanied by Fe²⁺ decrease. Both a* increase and Fe²⁺ decrease can be simulated by a diffusion model. Obtained diffusivity D _oxidation were about two orders of magnitude smaller than D _water . The a*-value increase after the oxidation in stage III appeared to be quasi-linear with time, indicating the zeroth order reaction …