View article

A rapid, highly sensitive method for detection of cross-connections between recycled and potable water in dual reticulation systems is required. The aim of this research was to determine the potential of fluorescence spectroscopy as a monitoring tool at three Australian dual distribution (drinking and recycled water) systems. Weekly grab samples of recycled and potable water were obtained over 12 weeks at each site and analysed for fluorescence excitation-emission matrix (EEM) spectroscopy, UV₂₅₄, dissolved organic carbon (DOC), electrical conductivity and pH. Fluorescence EEM spectroscopy was able to differentiate between recycled and potable water at each site by monitoring the protein-like fluorescence at peak T—an excitation-emission wavelength pair of λ_ex/em = 300/350 nm. While electrical conductivity was also able to distinguish between recycled and potable water, the differentiation was greatest …