Authors
Ram Manohar Yadav, Jingjie Wu, Raji Kochandra, Lulu Ma, Chandra Sekhar Tiwary, Liehui Ge, Gonglan Ye, Robert Vajtai, Jun Lou, Pulickel M Ajayan
Publication date
2015/6/10
Journal
ACS applied materials & interfaces
Volume
7
Issue
22
Pages
11991-12000
Publisher
American Chemical Society
Description
Oxygen reduction and evolution reactions are essential for broad range of renewable energy technologies such as fuel cells, metal-air batteries and hydrogen production through water splitting, therefore, tremendous effort has been taken to develop excellent catalysts for these reactions. However, the development of cost-effective and efficient bifunctional catalysts for both reactions still remained a grand challenge. Herein, we report the electrocatalytic investigations of bamboo-shaped carbon nitrogen nanotubes (CNNTs) having different diameter distribution synthesized by liquid chemical vapor deposition technique using different nitrogen containing precursors. These CNNTs are found to be efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions. The electrocatalytic activity strongly depends on the nanotube diameter as well as nitrogen functionality type. The higher diameter CNNTs are …
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