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As a consequence of the upcoming fourth Industrial Revolution, also known as Industry 4.0 (Industry 4.0), new disruptive technologies are being considered to be incorporated in the factory environment. One of these solutions are the Blockchain, which aims to integrate heterogeneous systems, manage commercial transactions and foster the assets’ traceability. Thus, this technology contributes to create a whole optimized supply chain that can impact in the global market. This chapter exposes the convergence of Blockchain and Industry 4.0. In this way, academical, commercial, and governmental initiatives are explored to present examples of what is currently being proposed, fostered and developed. In addition, a critical analysis covers the aspects of how these technologies can be synergically and efficiently integrated in a future society and industrial environment.