Authors
Nick Serpone, Daniele Dondi, Angelo Albini
Publication date
2007/2/15
Journal
Inorganica chimica acta
Volume
360
Issue
3
Pages
794-802
Publisher
Elsevier
Description
Minerals such as titanium dioxide, TiO2, and zinc oxide, ZnO, are well known active semiconductor photocatalysts used extensively in heterogeneous photocatalysis to destroy environmental pollutants that are organic in nature. They are also extensively used in sunscreen lotions as active broadband sunscreens that screen both UVB (290–320nm) and UVA (320–400nm) sunlight radiation and as high SPF makers. When so photoactivated by UV light, however, these two particular metal oxides are known to generate highly oxidizing radicals (OH and O2-) and other reactive oxygen species (ROS) such as H2O2 and singlet oxygen, 1O2, which are known to be cytotoxic and/or genotoxic. Hydroxyl (OH) radicals photogenerated from photoactive TiO2 specimens extracted from commercial sunscreen lotions [R. Dunford, A. Salinaro, L. Cai, N. Serpone, S. Horikoshi, H. Hidaka, J. Knowland, FEBS Lett. 418 (1997) 87 …
Total citations
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