Authors
Dmitry L Lakshtanov, Stanislav V Sinogeikin, Konstantin D Litasov, Vitali B Prakapenka, Holger Hellwig, Jingyun Wang, Carmen Sanches-Valle, Jean-Philippe Perrillat, Bin Chen, Maddury Somayazulu, Jie Li, Eiji Ohtani, Jay D Bass
Publication date
2007/8/21
Journal
Proceedings of the National Academy of Sciences
Volume
104
Issue
34
Pages
13588-13590
Publisher
National Academy of Sciences
Description
Silica is the most abundant oxide component in the Earth mantle by weight, and stishovite, the rutile-structured (P42/mnm) high-pressure phase with silica in six coordination by oxygen, is one of the main constituents of the basaltic layer of subducting slabs. It may also be present as a free phase in the lower mantle and at the core–mantle boundary. Pure stishovite undergoes a displacive phase transition to the CaCl2 structure (Pnnm) at ≈55 GPa. Theory suggests that this transition is associated with softening of the shear modulus that could provide a significant seismic signature, but none has ever been observed in the Earth. However, stishovite in natural rocks is expected to contain up to 5 wt % Al2O3 and possibly water. Here we report the acoustic velocities, densities, and Raman frequencies of aluminum- and hydrogen-bearing stishovite with a composition close to that expected in the Earth mantle at pressures …
Total citations
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Scholar articles
DL Lakshtanov, SV Sinogeikin, KD Litasov… - Proceedings of the National Academy of Sciences, 2007