Authors
Keerti Chauhan, Maurice Schmitt, Kurt Kremer, Peter Virnau, Kostas Daoulas
Publication date
2024/3/4
Journal
Bulletin of the American Physical Society
Publisher
American Physical Society
Description
Synthetic helical polymers are interesting for applications including catalysis, chirality recognition, and templating assembly of functional molecules. Some of these polymers, exhibit dynamic helicity: their conformations can randomly switch between left-and right-handed helical senses because of moderate inversion barriers. The helicity of dynamical polymers can be controlled [1] by" doping" their chain with small chiral groups. The influence of biasing groups on helicity has been investigated by mapping helical polymers onto generic 1D Ising models, which have explained [1] co-operative effects such as majority rules and sergeants-soldiers behavior. However 1D Ising models cannot describe the conformational properties of a polymer in three dimensional (3D) space. Therefore we develop a mesoscopic molecular model for dynamical helical polymers, combining the worm-like chain representation with special …
Scholar articles
K Chauhan, M Schmitt, K Kremer, P Virnau, K Daoulas - Bulletin of the American Physical Society, 2024