Authors
Julian Buchinger, Nikola Koutná, Zhuo Chen, Zaoli Zhang, Paul Heinz Mayrhofer, David Holec, Matthias Bartosik
Publication date
2019/6/15
Journal
Acta Materialia
Volume
172
Pages
18-29
Publisher
Pergamon
Description
Transition metal nitride thin films traditionally possess a low intrinsic fracture toughness. Motivated by the recently discovered fracture toughness enhancing superlattice (SL) effect, as well as the remarkably high potential for toughness predicted by theoretical studies for TiN/WN superlattices, we synthesise a series of these materials by DC reactive magnetron sputtering. The SL coatings demonstrate a vacancy-stabilised cubic configuration throughout, as well as a marginal lattice mismatch between the TiN and WN layers. All investigated mechanical properties produced a distinct dependence on the bilayer period, featuring a hardness peak of 36.7 ± 0.2 GPa and a minimum of the indentation modulus of 387 ± 2 GPa. The toughness-related quantities of the SLs in particular show a significant enhancement compared to monolithic TiN and WN, including a tripling of the fracture energy. The fracture toughness …
Total citations
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Scholar articles
J Buchinger, N Koutná, Z Chen, Z Zhang, PH Mayrhofer… - Acta Materialia, 2019