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Human activities and climate change constitute the contemporary catalyst for natural processes and their impacts, i.e., geo-environmental hazards. Globally, natural catastrophic phenomena and hazards, such as drought, soil erosion, quantitative and qualitative degradation of groundwater, frost, flooding, sea level rise, etc., are intensified by anthropogenic factors. Thus, they present rapid increase in intensity, frequency of occurrence, spatial density, and significant spread of the areas of occurrence. The impact of these phenomena is devastating to human life and to global economies, private holdings, infrastructure, etc., while in a wider context it has a very negative effect on the social, environmental, and economic status of the affected region. Geospatial technologies including Geographic Information Systems, Remote Sensing—Earth Observation as well as related spatial data analysis tools, models, databases, contribute nowadays significantly in predicting, preventing, researching, addressing, rehabilitating, and managing these phenomena and their effects. This review attempts to mark the most devastating geo-hazards from the view of environmental monitoring, covering the state of the art in the use of geospatial technologies in that respect. It also defines the main challenge of this new era which is nothing more than the fictitious exploitation of the information produced by the environmental monitoring so that the necessary policies are taken in the direction of a sustainable future. The review highlights the potential and increasing added value of geographic information as a means to support environmental monitoring in the face of climate …