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Metal−Organic Polyhedral Frameworks: High H₂ Adsorption Capacities and Neutron Powder Diffraction Studies

Authors

Yong Yan, Irvin Telepeni, Sihai Yang, Xiang Lin, Winfried Kockelmann, Anne Dailly, Alexander J Blake, William Lewis, Gavin S Walker, David R Allan, Sarah A Barnett, Neil R Champness, Martin Schroder

Publication date

2010/3/31

Journal

Journal of the American Chemical Society

Volume

132

Issue

Pages

4092-4094

Publisher

American Chemical Society

Description

Neutron powder diffraction experiments on D₂-loaded NOTT-112 reveal that the axial sites of exposed Cu(II) ions in the smallest cuboctahedral cages are the first, strongest binding sites for D₂ leading to an overall discrimination between the two types of exposed Cu(II) sites at the paddlewheel nodes. Thus, the Cu(II) centers within the cuboctahedral cage are the first sites of D₂ binding with a Cu−D₂ distance of 2.23(1) Å.

Total citations

Cited by 311

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Metal− organic polyhedral frameworks: high H2 adsorption capacities and neutron powder diffraction studies

Y Yan, I Telepeni, S Yang, X Lin, W Kockelmann… - Journal of the American Chemical Society, 2010