Authors
David J Janssen, Delphine Gilliard, Jörg Rickli, Philipp Nasemann, Andrea Koschinsky, Christel S Hassler, Andrew R Bowie, Michael J Ellwood, Charlotte Kleint, Samuel L Jaccard
Publication date
2023/2/1
Journal
Geochimica et Cosmochimica Acta
Volume
342
Pages
31-44
Publisher
Pergamon
Description
Special attention has been given to chromium (Cr) as a paleoproxy tracing redox cycling throughout Earth’s history, due to differences in the solubility of its primary redox species at Earth’s surface (Cr(III) and Cr(VI)) and isotope fractionation associated with their interconversion. In turn, chromium’s paleoproxy potential has motivated studies of the modern ocean to better understand which processes drive its cycling and to constrain their impact on the Cr isotope composition (δ53Cr) of seawater. Here, we present total dissolved seawater Cr concentrations and δ53Cr along the GEOTRACES GP13 section. This section is a zonal transect extending from Australia in the subtropical southwest Pacific Ocean. Surface signals of local biological Cr cycling are minimal, in agreement with distributions of dissolved major nutrients as well as biologically-controlled trace metals in this low productivity, oligotrophic environment …
Total citations
2023202443