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Planetary boundaries and their interactions pose severe challenges for global environmental governance due to their inherent uncertainties and complex multi-scale dynamics. Here we explore the global governance challenge posed by planetary boundaries interactions by focusing on the role of polycentric systems and order, a theoretical field that has gained much interest in the aftermath of claims of a stagnant UN-process. In the first part we work toward a clarification of polycentric order in an international context, and develop three propositions. We then present a case study of the emergence of international polycentricity to address interacting planetary boundaries, namely the climate change, ocean acidification and loss of marine biodiversity complex. This is done through a study of the Global Partnership on Climate, Fisheries and Aquaculture (PaCFA) initiative. As the case study indicates, a range of …