Authors
Chao Wei, Reshma R Rao, Jiayu Peng, Botao Huang, Ifan EL Stephens, Marcel Risch, Zhichuan J Xu, Yang Shao‐Horn
Publication date
2019/8
Source
Advanced Materials
Volume
31
Issue
31
Pages
1806296
Description
Electrochemical energy storage by making H2 an energy carrier from water splitting relies on four elementary reactions, i.e., the hydrogen evolution reaction (HER), hydrogen oxidation reaction (HOR), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Herein, the central objective is to recommend systematic protocols for activity measurements of these four reactions and benchmark activities for comparison, which is critical to facilitate the research and development of catalysts with high activity and stability. Details for the electrochemical cell setup, measurements, and data analysis used to quantify the kinetics of the HER, HOR, OER, and ORR in acidic and basic solutions are provided, and examples of state‐of‐the‐art specific and mass activity of catalysts to date are given. First, the experimental setup is discussed to provide common guidelines for these reactions, including the cell design …
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