Authors
Derek R Vardon, BK Sharma, John Scott, Guo Yu, Zhichao Wang, Lance Schideman, Yuanhui Zhang, Timothy J Strathmann
Publication date
2011/9/1
Journal
Bioresource technology
Volume
102
Issue
17
Pages
8295-8303
Publisher
Elsevier
Description
This study explores the influence of wastewater feedstock composition on hydrothermal liquefaction (HTL) biocrude oil properties and physico-chemical characteristics. Spirulina algae, swine manure, and digested sludge were converted under HTL conditions (300°C, 10–12MPa, and 30min reaction time). Biocrude yields ranged from 9.4% (digested sludge) to 32.6% (Spirulina). Although similar higher heating values (32.0–34.7MJ/kg) were estimated for all product oils, more detailed characterization revealed significant differences in biocrude chemistry. Feedstock composition influenced the individual compounds identified as well as the biocrude functional group chemistry. Molecular weights tracked with obdurate carbohydrate content and followed the order of Spirulina<swine manure<digested sludge. A similar trend was observed in boiling point distributions and the long branched aliphatic contents. These …
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