Authors
Yulin Qi, Mark P Barrow, Huilin Li, Joseph E Meier, Steve L Van Orden, Christopher J Thompson, Peter B O’Connor
Publication date
2012/3/20
Journal
Analytical chemistry
Volume
84
Issue
6
Pages
2923-2929
Publisher
American Chemical Society
Description
The Fourier transform spectrum can be presented in the absorption-mode (commonly used in FT-NMR), magnitude-mode (FT-ICR), and power-mode (engineering applications). As is routinely used in FT-NMR, it is well-known that the absorption-mode display gives a much narrower peak shape which greatly improves the spectrum; recently, the successful solution of the phase equation allowed broadband phase correction which makes it possible to apply the absorption-mode routinely in FT-ICR. With the empirical evidence provided herein, it has been confirmed that in addition to the improvement on resolving power, compared to the conventional magnitude-mode, the new absorption-mode improves the signal-to-noise ratio (S/N) of a spectrum by 1.4-fold and can improve the mass accuracy up to 2-fold with no extra cost in instrumentation. Therefore, it is worthwhile to apply and promote absorption-mode in …
Total citations
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Scholar articles
Y Qi, MP Barrow, H Li, JE Meier, SL Van Orden… - Analytical chemistry, 2012