Authors
YL Sun, ZF Wang, Wei Du, Qian Zhang, QQ Wang, PQ Fu, XL Pan, Jiaohong Li, John Jayne, DR Worsnop
Publication date
2015/9/11
Journal
Atmospheric Chemistry and Physics
Volume
15
Issue
17
Pages
10149-10165
Publisher
Copernicus GmbH
Description
High concentrations of fine particles (PM are frequently observed during all seasons in Beijing, China, leading to severe air pollution and human health problems in this megacity. In this study, we conducted real-time measurements of non-refractory submicron aerosol (NR-PM species (sulfate, nitrate, ammonium, chloride, and organics) in Beijing using an Aerodyne Aerosol Chemical Speciation Monitor for 1 year, from July 2011 to June 2012. This is the first long-term, highly time-resolved ( 15 min) measurement of fine particle composition in China. The seasonal average (1 mass concentration of NR-PM ranged from 52 (49) µg m in the spring season to 62 (49) µg m in the summer season, with organics being the major fraction (40–51 %), followed by nitrate (17–25 %) and sulfate (12–17 %). Organics and chloride showed pronounced seasonal variations, with much higher concentrations in winter than in the other seasons, due to enhanced coal combustion emissions. Although the seasonal variations of secondary inorganic aerosol (SIA, i.e., sulfate nitrate ammonium) concentrations were not significant, higher contributions of SIA were observed in summer (57–61 %) than in winter (43–46 %), indicating that secondary aerosol production is a more important process than primary emissions in summer. Organics presented pronounced diurnal cycles that were similar among all seasons, whereas the diurnal variations of nitrate were mainly due to the competition between photochemical production and gas–particle partitioning. Our data also indicate that high concentrations of NR-PM ( 60 µg m are usually …
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