Authors
Aleksandr I Chumakov, Giulio Monaco, Aldo Fontana, Alexey Bosak, Raphaël P Hermann, Dimitrios Bessas, Björn Wehinger, Wilson A Crichton, Michael Krisch, Rudolf Rüffer, Giacomo Baldi, Giovanni Carini Jr, Giuseppe Carini, Giovanna D’Angelo, Edmondo Gilioli, Gaspare Tripodo, Marco Zanatta, Björn Winkler, Victor Milman, Keith Refson, Martin Dove, Natalia Dubrovinskaia, Leonid Dubrovinsky, Ralf Keding, Yuanzheng Yue
Publication date
2014
Description
We measured the density of vibrational states (DOS) and the specific heat of various glassy and crystalline polymorphs of . The typical (ambient) glass shows a well-known excess of specific heat relative to the typical crystal (-quartz). This, however, holds when comparing a lower-density glass to a higher-density crystal. For glassy and crystalline polymorphs with matched densities, the DOS of the glass appears as the smoothed counterpart of the DOS of the corresponding crystal; it reveals the same number of the excess states relative to the Debye model, the same number of all states in the low-energy region, and it provides the same specific heat. This shows that glasses have higher specific heat than crystals not due to disorder, but because the typical glass has lower density than the typical crystal.
Total citations
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Scholar articles
AI Chumakov, G Monaco, A Fontana, A Bosak… - Physical Review Letters, 2014