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Transparent Fe_1–xNi_xOOH overlayers (∼2 nm thick) were deposited photoelectrochemically on (001) oriented heteroepitaxial Sn- and Zn-doped hematite (α-Fe₂O₃) thin film photoanodes. In both cases, the water photo-oxidation performance was improved by the cocatalyst overlayers. Intensity modulated photocurrent spectroscopy (IMPS) was applied to study the changes in the hole current and recombination current induced by the overlayers. For the Sn-doped hematite photoanode, the improvement in performance after deposition of the Fe_1–xNi_xOOH overlayer was entirely due to reduction in the recombination current, leading to a cathodic shift in the onset potential. For the Zn-doped hematite photoanode, in addition to a reduction in recombination current, an increase in the hole current to the surface was also observed after the overlayer deposition, leading to a cathodic shift in the onset potential as well as …