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The successful assembly of large supramolecular structures infers a delicate balance between reversible noncovalent interactions which are capable of undergoing correction and reassembly, stereochemical features (chirality), and conformational flexibility.(1) The goal of the supramolecular chemist is to synthesize the simplest molecular structures that are able to form supramolecular assemblies with novel functions that cannot be fulfilled by a single molecule or collection of molecules. The functions that arise from these supramolecular architectures can be as diverse as novel magnetic and optical properties, catalysis, molecular recognition, and transport processes.(2-6) While many excellent reviews focused on the synthesis and characterization of supramolecular architectures from a structural point of view with the aim to design complex supramolecular assemblies inspired by nature, very few have adventured …