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We present an experimental technique, that we refer to as ‘thermographic particle velocimetry’ (TPV), which is capable of the simultaneous measurement of two-dimensional (2-D) surface temperature and velocity at the interface of multiphase flows. The development of the technique has been motivated by the need to study gravity-driven liquid-film flows over inclined heated substrates, however, the same measurement principle can be applied for the recovery of 2-D temperature- and velocity-field information at the interface of any flow with a sufficient density gradient between two fluid phases. The proposed technique relies on a single infrared (IR) imager and is based on the employment of highly reflective (here, silver-coated) particles which, when suspended near or at the interface, can be distinguished from the surrounding fluid domain due to their different emissivity. Image processing steps used to recover the …