Authors
Yanping Zhou, Wenping Sun, Xianhong Rui, Yan Zhou, Wun Jern Ng, Qingyu Yan, Eileen Fong
Publication date
2016/1/13
Journal
Nano Energy
Volume
21
Pages
71-79
Publisher
Elsevier
Description
Transitional metal oxides are promising anode materials for sodium ion batteries (SIBs) due to their high theoretical capacities and material abundance; however, their sodium storage capability is significantly hindered by the sluggish sodiation/desodiation reaction kinetics. Herein, towards achieving fast and durable sodiation/desodiation reaction, Fe3O4 and Co3O4 nanocrystals encapsulated in carbon micro-spheres are synthesized via a biochemistry approach using recombinant elastin-like polypeptides containing hexahistidine tag (ELP16-His) followed by annealing. Fe3O4 and Co3O4 nanocrystals of approximately 5 nm in size, which are uniformly dispersed in a carbon matrix, are obtained. The carbon-encapsulated metal oxides exhibit encouraging sodium storage capacities (657 and 246 mA h g−1 at 0.1 and 2 A g−1, respectively, for carbon-encapsulated Fe3O4; 583 and 183 mA h g−1 at 0.1 and 2 A g−1 …
Total citations
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