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The rate of Fe(III) reductive dissolution by ascorbate has been shown by [Larsen, O. and Postma, D., 2001. Kinetics of reductive bulk dissolution of lepidocrocite, ferrihydrite and goethite. Geochim. Cosmochim. Acta, 65: 1367–1379.] to decrease in the order ferrihydrite>lepidocrocite>goethite>hematite. The abiotic rate of reductive dissolution thus correlates with the solubility of the iron oxyhydroxides. We investigated whether this also holds for the microbial reduction kinetics of Fe(III) iron oxyhydroxides. The solubilities of nanoparticulate hematite, lepidocrocite, ferrihydrite and amorphous Fe(III) oxyhydroxide were obtained from pe–pH titrations of oxyhydroxide/Fe²⁺(aq) suspensions, in pH range 4 to 7. The solubility of low surface area (LSA) hematite was estimated from redox potential measurements at pH 2. The same solid phases and soluble Fe(III)-citrate were then reduced by the iron reducing bacterium …