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To separate and concentrate NH⁴⁺ and PO₄ ^3– from the synthetic wastewater to the concentrated solution through a novel electrochemical reactor with circulated anode and cathode using the difference of the concentration between electrode chamber and middle chamber.In recent years, the research on electrochemical processes have been focused on phosphate and ammonium removal and recovery. Among the wide range of possibilities with regards to electrochemical processes, capacitive deionization (CDI) saves the most energy while at the same time does not have continuity and selectivity. In this study, a new electrochemical reactor with electrolyte cyclic flowing in the electrode chambers was constructed to separate and concentrate phosphate and ammonium continuously and selectively from wastewater, based on the principle of CDI. At the concentration ratio of NaCl solution …