Authors
J Sermeus, R Sinha, K Vanstreels, PM Vereecken, C Glorieux
Publication date
2014/7/14
Journal
Journal of Applied Physics
Volume
116
Issue
2
Publisher
AIP Publishing
Description
MnO 2 is a material of interest in the development of high energy-density batteries, specifically as a coating material for internal 3D structures, thus ensuring rapid energy deployment. Its electrochemical properties have been mapped extensively, but there are, to the best of the authors' knowledge, no records of the elastic properties of thin film MnO 2. Impulsive stimulated thermal scattering (ISTS), also known as the heterodyne diffraction or transient grating technique, was used to determine the Young's modulus (E) and porosity (ψ) of a 500 nm thick MnO 2 coating on a Si (001) substrate. ISTS is an all optical method that is able to excite and detect surface acoustic waves (SAWs) on opaque samples. From the measured SAW velocity dispersion, the Young's modulus and porosity were determined to be E= 25±1 GPa and ψ= 42±1%⁠, respectively. These values were confirmed by independent techniques and …
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