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Pursuing economic, environmental and social sustainability requires networks endowed with persistent relationships between stakeholders. Networks serve as the vehicle to coordinate diverse policy goals among stakeholders. Within the networks, stakeholders inevitably experience some level of distrust due to the complexity and uncertainty of the unstructured problems on the sustainability. However, little is known about why stakeholders often distrust with one another in the networks. By analysing a local fracking policy network in NYS, we suggest that distrust is influenced by incongruent ecological worldviews, policy goals incongruence in the triple bottom line of sustainability, characterization framing, policy communications and knowledge exchange.