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An analytical procedure involving sequential chemical ex-tractions has been developed for the partitioning of particulate trace metals (Cd, Co, Cu, Ni, Pb, Zn, Fe, and Mn) into five fractions: exchangeable, bound to carbonates, bound to Fe-oxides, bound to organic matter, and residual. Ex-perimental results obtained on replicate samples of fluvial bottom sediments demonstrate that the relative standard deviation of the sequential extraction procedure is generally better than±10%. The accuracy, evaluated by comparing total trace metal concentrations with the sum of the five individual fractions, proved to be satisfactory. Complementary measurements were performed on the individual leachates, and on the residual sediments following each extraction, to evaluate the selectivity of the various reagents toward specific geochemical phases. An application of the proposed method to river sediments is described, and the …