View article

The structure of the hydrated gallium(III), indium(III), and chromium(III) ions has been determined in aqueous perchlorate and nitrate solutions by means of the large-angle X-ray scattering (LAXS) and extended X-ray absorption fine structure (EXAFS) techniques. The EXAFS studies have been performed over a wide concentration range, 0.005−1.0 mol·dm^-3 (2.6 mol·dm^-3 for chromium(III)), while the LAXS studies are restricted to concentrated solutions, ca. 1.5 mol·dm^-3. All three metal ions were found to coordinate six water molecules, each of which are hydrogen bonded to two water molecules in a second hydration sphere. The metal−oxygen bond distance in the first hydration sphere of the gallium(III), indium(III), and chromium(III) ions was determined by LAXS and EXAFS methods to be 1.959(6), 2.131(7), and 1.966(8) Å. The LAXS data gave mean second sphere M···O distances of 4.05(1), 4.13(1), and 4.08(2) Å …