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Melting experiments were performed on the Fe‐C‐H system to 127 GPa in a laser‐heated diamond anvil cell. On the basis of in situ and ex situ sample characterizations, we found that the solubility of carbon in liquid Fe correlates inversely with hydrogen concentration at ~60 GPa and ~3500 K, indicating that liquid Fe preferentially incorporates hydrogen rather than carbon under conditions with abundant C and H. While large amounts of both C and H may have been delivered to the growing Earth, C‐poor/H‐rich metals were likely added to the protocore in the late stages of core formation. We also obtained a melting curve of FeH_x (x > 1) far beyond the pressure range in earlier determinations. Its liquidus temperature was found to be 2380 K at 135 GPa, lower than those of Fe alloyed with the other possible core light elements. Relatively low core temperature is thus supported by the presence of hydrogen.