Authors
Amit Das, Alireza Rahimi, Arne Ulbrich, Manar Alherech, Ali Hussain Motagamwala, Aditya Bhalla, Leonardo da Costa Sousa, Venkatesh Balan, James A Dumesic, Eric L Hegg, Bruce E Dale, John Ralph, Joshua J Coon, Shannon S Stahl
Publication date
2018/1/19
Journal
ACS Sustainable Chemistry & Engineering
Volume
6
Issue
3
Pages
3367-3374
Publisher
American Chemical Society
Description
Diverse lignin samples have been subjected to a catalytic aerobic oxidation process, followed by formic-acid-induced hydrolytic depolymerization. The yield of monomeric aromatic compounds varies depending on the lignin plant source and pretreatment method. The best results are obtained from poplar lignin isolated via a acidolysis pretreatment method, which gives 42 wt% yield of low-molecular-weight aromatics. Use of other pretreatment methods and/or use of maple and maize lignins afford yields of aromatics ranging from 3 to 31 wt%. These results establish useful references for the development of improved oxidation/depolymerization protocols.
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