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This study analyzed the network characteristics of successful and unsuccessful national teams that participated in FIFA World Cup 2014. The relationship between the variables of overall team performance and the network characteristics measured on the basis of the passes between teammates was also investigated. A dataset of 37,864 passes between teammates in 64 soccer matches enabled the study on network structure and team performance of 32 national soccer teams. Our results showed significant differences in the dependent variables of network density (F_4,123 = 2.72; p = 0.03; η²_p = 0.04; small effect size) and total links (F_4,123 = 2.73; p = 0.03; η²_p = 0.04; small effect size) between the teams that reached the later stages of the tournament. Goals scored presented a small positive correlation with total links (r = 0.24; p = 0.001), network density (r = 0.24; p = 0.001), and clustering coefficient (r = 0.17; p > 0 …