Authors
JW Somerville, RA House, N Tapia-Ruiz, A Sobkowiak, S Ramos, AV Chadwick, MR Roberts, U Maitra, PG Bruce
Publication date
2018
Journal
Journal of Materials Chemistry A
Volume
6
Issue
13
Pages
5271-5275
Publisher
Royal Society of Chemistry
Description
The composition space between MnO2, NaFeO2, and Na[Ni1/2Mn1/2]O2 has been explored with the goal of identifying Earth-abundant single-phase P2 cathode materials. This has led to the identification of two compounds, P2-Na2/3[Ni1/3−y/2Mn2/3−y/2Fey]O2 (y = 1/6, 1/3) which exhibit state of the art specific energies. These materials were further evaluated through galvanostatic cycling and X-ray absorption spectroscopy.
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