Authors
Mei Wang, Lin Chen, Licheng Sun
Publication date
2012
Source
Energy & Environmental Science
Volume
5
Issue
5
Pages
6763-6778
Publisher
Royal Society of Chemistry
Description
This perspective article reviews the recent important progress in electrocatalytic hydrogen production catalyzed by earth-abundant metal complexes. The catalysts are divided into two categories depending on the media used in the hydrogen-evolving reactions, with an emphasis on the types of acids employed. The catalysts used in the first category, which work in organic solutions, include nickel and cobalt complexes with base-containing diphosphine ligands, cobaloximes, cobalt tetrapyridine complexs, and [NiFe]- and [FeFe]-hydrogenase mimics. Molybdenum and cobalt pentapyridine complexes, as well as the cobalt bis(iminopyridine) complex reported very recently, are the most important examples of catalysts used in the second category, which work in aqueous solutions. The advantages and disadvantages of the different types of catalysts are discussed and the hydrogen-evolving mechanisms for the well …
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