Authors
Na Liu, Ming L Tang, Mario Hentschel, Harald Giessen, A Paul Alivisatos
Publication date
2011/8
Journal
Nature materials
Volume
10
Issue
8
Pages
631-636
Publisher
Nature Publishing Group UK
Description
Metallic nanostructures possess plasmonic resonances that spatially confine light on the nanometre scale. In the ultimate limit of a single nanostructure, the electromagnetic field can be strongly concentrated in a volume of only a few hundred nm3 or less. This optical nanofocus is ideal for plasmonic sensing. Any object that is brought into this single spot will influence the optical nanostructure resonance with its dielectric properties. Here, we demonstrate antenna-enhanced hydrogen sensing at the single-particle level. We place a single palladium nanoparticle near the tip region of a gold nanoantenna and detect the changing optical properties of the system on hydrogen exposure by dark-field microscopy. Our method avoids any inhomogeneous broadening and statistical effects that would occur in sensors based on nanoparticle ensembles. Our concept paves the road towards the observation of single catalytic …
Total citations
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Scholar articles
N Liu, ML Tang, M Hentschel, H Giessen, AP Alivisatos - Nature materials, 2011