Authors
Muhammad Khairud Dahri, Muhammad Raziq Rahimi Kooh, Linda BL Lim
Publication date
2015/12/1
Journal
Alexandria Engineering Journal
Volume
54
Issue
4
Pages
1253-1263
Publisher
Elsevier
Description
This study investigated the potential of Casuarina equisetifolia needle (CEN) on the removal of two important dyes, methylene blue (MB) and malachite green (MG), by batch adsorption experiments. Characterisation of CEN’s functional groups was done using Fourier Transform infrared spectroscopy while elemental analysis was carried out using CHNS analysis and X-ray fluorescence. The experiments were carried out by varying the adsorbent dosage, pH, ionic strength, contact time and initial dye concentration. The pseudo-second-order kinetics model best represented the experimental data for both CEN-MB and CEN-MG systems. The Weber–Morris intraparticle diffusion model showed that intraparticle diffusion is not the rate-limited step for both adsorbates, while the Boyd model suggested both systems could be controlled by film diffusion. The Langmuir, Freundlich and Dubinin–Radushkevich isotherm …
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