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This Short Review describes recent developments in cobalt-catalyzed enantioselective C–C bond-forming reactions. The article focuses on reactions that most likely involve chiral organocobalt species as crucial catalytic intermediates and their mechanistic aspects.

1 Introduction

2 Hydrovinylation

3 C–H Functionalization

4 Cycloaddition and Cyclization

5 Addition of Carbon Nucleophiles

6 Cross-Coupling

7 Conclusion