Authors
Robert J Wild, Peter M Edwards, William P Dubé, Karsten Baumann, Eric S Edgerton, Patricia K Quinn, James M Roberts, Andrew W Rollins, Patrick R Veres, Carsten Warneke, Eric J Williams, Bin Yuan, Steven S Brown
Publication date
2014/8/19
Journal
Environmental science & technology
Volume
48
Issue
16
Pages
9609-9615
Publisher
American Chemical Society
Description
We present a sensitive, compact detector that measures total reactive nitrogen (NOy), as well as NO2, NO, and O3. In all channels, NO2 is directly detected by laser diode based cavity ring-down spectroscopy (CRDS) at 405 nm. Ambient O3 is converted to NO2 in excess NO for the O3 measurement channel. Likewise, ambient NO is converted to NO2 in excess O3. Ambient NOy is thermally dissociated at ∼700 °C to form NO2 or NO in a heated quartz inlet. Any NO present in ambient air or formed from thermal dissociation of other reactive nitrogen compounds is converted to NO2 in excess O3 after the thermal converter. We measured thermal dissociation profiles for six of the major NOy components and compared ambient measurements with other instruments during field campaigns in Utah and Alabama. Alabama measurements were made in a rural location with high biogenic emissions, and Utah measurements …
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