Authors
SM Pike, KO Buesseler, J Andrews, N Savoye
Publication date
2005/1/17
Journal
Journal of Radioanalytical and Nuclear Chemistry
Volume
263
Issue
2
Pages
355-360
Publisher
Akadémiai Kiadó, co-published with Springer Science+ Business Media BV, Formerly Kluwer Academic Publishers BV
Description
Development of a small volume (2-4 liter) technique for measuring 234 Th in sea water has been instrumental in bringing to light small-scale structures in upper-ocean particle removal processes previously missed by standard 234 Th measurement techniques. Further development of this method to evaluate removal efficiencies of 234 Th via MnO 2 precipitation quantified using ICP-MS are presented in this work. Advantages to this approach are precise knowledge of 234 Th recovery, while maintaining high sample throughput afforded by ICP-MS analyzes. The improved technique includes the acidification of 4-liter sea water samples and the addition of 230 Th as a yield monitor prior to MnO 2 precipitation. Subsequent filtration and beta-counting of the high-energy daughter, 234m Pa, was …
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