Authors
Ram B Ambre, Quentin Daniel, Ting Fan, Hong Chen, Biaobiao Zhang, Lei Wang, Mårten SG Ahlquist, Lele Duan, Licheng Sun
Publication date
2016
Journal
Chemical Communications
Volume
52
Issue
100
Pages
14478-14481
Publisher
Royal Society of Chemistry
Description
Iron porphyrins Fe-pE, Fe-mE, and Fe-oE were synthesized and their electrochemical behavior for CO2 reduction to CO has been investigated. The controlled potential electrolysis of Fe-mE gave exclusive 65% Faradaic efficiency (FE) whereas Fe-oE achieved quasi-quantitative 98% FE (2% H2) for CO production.
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