Authors
Mahmood Rahmati, Baiyu Huang, Max K Mortensen Jr, Kamyar Keyvanloo, Thomas H Fletcher, Brian F Woodfield, William C Hecker, Morris D Argyle
Publication date
2018/3/1
Journal
Journal of Catalysis
Volume
359
Pages
92-100
Publisher
Academic Press
Description
Four identically-prepared 20 wt% cobalt/0.15 wt% ruthenium Fischer-Tropsch catalysts, supported on different aluminas, were synthesized by incipient wetness impregnation, characterized, and compared based on their performance under standard Fischer-Tropsch synthesis conditions. Three alumina supports were obtained from commercial sources (Sasol, St. Gobain, and Alfa Aesar), while the fourth was made using a published technique that included 5 wt% silica. The silica-stabilized alumina catalyst produced superior Fischer-Tropsch rates of 49 mmol CO/gcat h, compared to the other catalysts on the commercial supports with rates of 26–39 mmol CO/gcat h. The improved performance of the silica-stabilized alumina support compared to the commercially available aluminas is ascribed to a bimodal pore structure with larger average diameters and enhanced thermal stability. The support can be …
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