Authors
Zhengyu He, Kuang He, Alex W Robertson, Angus I Kirkland, Dongwook Kim, Jisoon Ihm, Euijoon Yoon, Gun-Do Lee, Jamie H Warner
Publication date
2014/7/9
Journal
Nano letters
Volume
14
Issue
7
Pages
3766-3772
Publisher
American Chemical Society
Description
We present an atomic resolution structural study of covalently bonded dopant pairs in the lattice of monolayer graphene. Two iron (Fe) metal atoms that are covalently bonded within the graphene lattice are observed and their interaction with each other is investigated. The two metal atom dopants can form small paired clusters of varied geometry within graphene vacancy defects. The two Fe atoms are created within a 10 nm diameter predefined location in graphene by manipulating a focused electron beam (80 kV) on the surface of graphene containing an intentionally deposited Fe precursor reservoir. Aberration-corrected transmission electron microscopy at 80 kV has been used to investigate the atomic structure and real time dynamics of Fe dimers embedded in graphene vacancies. Four different stable structures have been observed; two variants of an Fe dimer in a graphene trivacancy, an Fe dimer embedded …
Total citations
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Scholar articles
Z He, K He, AW Robertson, AI Kirkland, D Kim, J Ihm… - Nano letters, 2014