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A new microstructure-informed three-scale homogenization scheme for elasto-viscoplastic heterogeneous materials is developed. It is applied to predict the mechanical behavior of cast duplex austenitic-ferritic (AF) steels, which are widely used in primary loop of pressurized water reactors (PWR). At the first scale (microscale), the elasto-viscoplastic behavior of single crystals for both phases is modeled using linear elasticity and a viscoplastic crystal plasticity model. An “affine” type formulation based on the first moments of stresses is applied to the inelastic non-linear part of the deformation. Then, at the second scale (mesoscale), an EBSD-informed two-phase austenite/ferrite laminate structure (LS) model is developed with {110}-type habit planes (HP) in ferrite and a Kurdjumov-Sachs orientation relationship (KS-OR) between both phases. At the third scale (macroscale), the model considers a single ferritic primary …