Authors
YN Mata, ML Blazquez, A Ballester, F Gonzalez, JA Munoz
Publication date
2008/10/30
Journal
Journal of hazardous materials
Volume
158
Issue
2-3
Pages
316-323
Publisher
Elsevier
Description
The recovery of cadmium, lead and copper with the brown alga Fucus vesiculosus was characterized and quantified. The biosorption data fitted the pseudo-second order and Langmuir isotherm models, but did not adjust to the intraparticle diffusion model. The metal uptakes deduced from the pseudo-second order kinetic model and the Langmuir isotherm model followed a similar sequence: Cu>Cd≈Pb. The Langmuir maximum metal uptakes were: 0.9626mmol/g, Pb 1.02mmol/g, and Cu 1.66mmol/g. According to the equilibrium constants of this isotherm model, the affinity of metals for the biomass followed this order: Pb>Cu>Cd. Biosorption was accomplished by ion exchange between metals in solution and algal protons, calcium and other light metals, and by complexation of the adsorbed metals with algal carboxyl groups. FTIR spectra showed a shift in the bands of carboxyl, hydroxyl and sulfonate groups.
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