Authors
Anirban Mondal, J Aneesh, Vikash Kumar Ravi, Rituraj Sharma, Wasim J Mir, Mathew C Beard, Angshuman Nag, KV Adarsh
Publication date
2018/9/15
Journal
Physical Review B
Volume
98
Issue
11
Pages
115418
Publisher
American Physical Society
Description
Defect-tolerant perovskite nanocrystals of the general formula Cs-Pb- (where , Br, and I) have shown exceptional potential in fundamental physics as well as in novel optoelectronic applications as the next generation of solar cells. Although exciton many-body interactions such as biexciton Stark shift, state filling, and Auger recombination are studied extensively, other important correlated effects, such as band gap renormalization (BGR) and hot-phonon bottleneck, are not explored in these nanocrystals. Here we experimentally demonstrate the carrier density dependence of the BGR and an effective hot-phonon bottleneck in mixed-halide nanocrystals. The results are compared with two other halide compositions, namely, and nanocrystals with varying band gaps. The optical response of the nanocrystals changes dramatically across the spectral range of many hundreds of meV …
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