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Similarity comparisons are a basic component of cognition, and there are many elegant models of this process. None of these models describe comparisons of structured representations, although mounting evidence suggests that mental representations are well characterized by structured hierarchical systems of relations. We propose that structured representations can be compared via structural alignment, a process derived from models of analogical reasoning. The general prediction of structural alignment is that similarity comparisons lead subjects to attend to the matching relational structure in a pair of items. This prediction is illustrated with a computational simulation that also suggests that the strength of the relational focus is diminished when the relational match is impoverished, or when competing interpretations lead to rich object matches. These claims are tested in four experiments using the one-shot …