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Lack of societal acceptance of energy (transition) technologies is often attributed to a lack of knowledge among the public. The underlying assumption is that more knowledge improves attitudes about a technology. This assumption will be tested in this paper by examining the influence of the scores on a CCS Knowledge Test on attitudes towards CO2 capture and storage (CCS). Furthermore the paper will examine the influen towards CCS and will analyse how knowledge and perceptions jointly influence attitude as well as in interaction. Implications of the results for communication about CCS are discussed.