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Direct Air Capture with Carbon Storage (DACCS) technologies represent one of the most significant potential tools for tackling climate change by making net-zero and net-negative emissions achievable, as deemed necessary in reports from the Intergovernmental Panel on Climate Change and the European Green Deal. We draw from a novel and original dataset of expert interviews (N = 125) to distil ten recommendations for future DACCS policy. After providing a literature review on DACCS and explaining our methods of data collection, we present these recommendations as follows: (a) follow governance principles that ensure ‘negative’ emissions; (b) prioritize long-term carbon storage; (c) appreciate and incentivize scale; (d) co-develop with capture, transport, and storage; (e) phase in a carbon price; (f) couple with renewables; (g) harness hub deployment; (h) maintain separate targets; (i) embrace certification …