Authors
Michelle P Browne, Hugo Nolan, Georg S Duesberg, Paula E Colavita, Michael EG Lyons
Publication date
2016/4/1
Journal
ACS Catalysis
Volume
6
Issue
4
Pages
2408-2415
Publisher
American Chemical Society
Description
Mixed Mn/Ru oxide thermally prepared electrodes using different compositions of Mn and Ru precursor salts have been fabricated on Ti supports via thermal decomposition at two annealing temperatures. Subsequently, the oxygen evolution reaction (OER) activities of these electrodes were determined. A majority of the mixed Mn/Ru catalysts are highly active for the OER, exhibiting lower overpotential values compared to those of the state-of-the-art RuO2 and IrO2 type materials, when measured at a current density of 10 mA cm–2. These Mn/Ru oxide materials are also cheaper to produce than the aforementioned platinum group materials, therefore rendering the Mn/Ru materials more practical and economical. The Mn/Ru catalysts are also evaluated with respect to their Tafel slopes and turnover frequency numbers. Interestingly, scanning electron microscopy reveals that the morphologies of the electrodes …
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