Authors
Natacha Krins, Frédéric Hatert, Karl Traina, Laurent Dusoulier, Isabel Molenberg, Jean-François Fagnard, Ph Vanderbemden, André Rulmont, Rudi Cloots, Bénédicte Vertruyen
Publication date
2006/4/1
Journal
Solid State Ionics
Volume
177
Issue
11-12
Pages
1033-1040
Publisher
Elsevier
Description
LiMn2−xTixO4 compounds with 0≤x≤1 were prepared by solid state reaction and Pechini technique. Powder X-ray diffraction showed that all samples crystallize with the spinel crystal structure (S.G. Fd3¯m). The cubic unit-cell parameter increases with the Ti content. The influence of the Ti content and cationic distribution on the magnetic properties of the compounds was studied by measuring the temperature and magnetic field dependences of the magnetization: substitution by non-magnetic d0 Ti4+ ions appeared to weaken the magnetic interactions between the manganese ions. The electrical properties of LiMnTiO4 were studied by AC impedance spectroscopy and DC polarisation measurements, which revealed the electronic character of the conduction process.
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